Three-dimensional homochiral transition-metal camphorate architectures directed by a flexible auxiliary ligand.
Three-dimensional homochiral transition-metal camphorate architectures directed by a flexible auxiliary ligand.
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DOI：
10.1021/ic800195u
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发表时间：
2008-04
影响因子：
4.6
通讯作者：
Jian Zhang;Emily Chew;Shumei Chen;Jimmy T H Pham;X. Bu
中科院分区：
文献类型：
--
作者：
Jian Zhang;Emily Chew;Shumei Chen;Jimmy T H Pham;X. Bu
本文报道了由过渡金属(Fe2+、Co2+和Ni2+)、刚性对映体樟脑酸和柔性4，4‘-三亚甲基联吡啶组装而成的四个同手性和一个外消旋的手性化合物，它们的特点是一个不寻常的同手性三维超分子组装(由4-连接的双层连接而成)，以及一个同手性的3层互穿金刚石网和一个不互穿的原始立方网。
Reported here are four homochiral and one racemic chiral compounds assembled from transition metals (Fe2+, Co2+, and Ni2+), rigid enantiopure camphoric acid, and flexible 4,4'-trimethylenedipyridine; they feature an unusual homochiral three-dimensional supramolecular assembly (resulting from catenation of 4-connected bilayers) as well as a homochiral 3-fold interpenetrating diamond net and a noninterpenetrating primitive cubic net.