DEVELOPMENT OF THE NON-EQUILIBRIUM REACTIVE CHEMICAL TRANSPORT CODE CHMTRNS
DEVELOPMENT OF THE NON-EQUILIBRIUM REACTIVE CHEMICAL TRANSPORT CODE CHMTRNS
复制标题
非平衡反应化学物质传输代码 CHMTRNS 的开发
DOI：
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发表时间：
1987
期刊：
影响因子：
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通讯作者：
L. Benson
中科院分区：
文献类型：
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作者：
J. Noorishad;C. Carnahan;L. Benson
............................................................ v Introduction .................................... ., .... " ................ 1 Theoretical Basis .................................... ." .. ".............. 3 Equilibrium Formulation ........................................ 3 Non-Equilibrium Formulation .................................... 7 Oxidation-Reduction Reactions .................................. 8 Carbon Isotope Fractionation ................................... 9 Heat Transport Formulation .................................... 13 Solution Approach ................................................... 15 Space and Time Discretization ................................. 16 Implementation of Boundary Conditions ......................... 19 Solution Methods .............................................. 22 Treatment of Dissolution and Precipitation .................... 24 Applications ........................................................ 25 Simulation of Reversible Non-Equilibrium Dissolution of Calcite in CO 2 -Water Systems 25 Simulation of Kinetic Silica-Water Reactions .................. 30 Simulation of Non-Reversible Kinetic Dissolution of Glass .................................................... 37 Simulation of Non"Isothermal Oxidation-Reduction During Transport ............................................ 42 S · 1· f l3 C F . . D . lmu atlon 0 ractlonatlon urlng Non-Equilibrium Reactive Solute Transport in Geologic Systems ............................................ 48 Conclusion ........................................................... 63 Acknowledgements .................................................... 63 References .......................................................... 65 Appendices: Inputs and Outputs of Solved Problems .................. 69 Appendix 1 Soil Water Composition: Input and Output ......... 71 Appendix 2 Kinetic Dissolution of Calcite During Reactive Transport: Input and Output ....................... 75 Appendix 3 Equilibrium Calcite Dissolution During Reactive Transport: Input and Sample Output ......................... 85 Appendix 4 Kinetic Calcite Dissolution in Batch Reactions: Input and Sample Output .................................... 93
