Rh-catalyzed sulfonic acid group directed ortho C-H olefination of arenes.

Rh-catalyzed sulfonic acid group directed ortho C-H olefination of arenes.
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DOI:
10.1039/c3cc44690e
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发表时间:
2013-08
影响因子:
4.9
通讯作者:
Yi Dong;Gang Liu
Yi Dong;Gang Liu
中科院分区:
化学2区
文献类型:
--
作者:
Yi Dong;Gang Liu

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开发了Rh催化的磺酸基引导的芳烃邻位C-H烯化反应,产率高,反应范围宽。催化剂的有效性能使这种贫电子的芳香C-H有效地活化,未活化的烯烃也适用于该反应。
A Rh-catalyzed ortho C-H olefination of arenes directed by a sulfonic acid group was developed with good yields and a broad reaction scope. Efficient performance of the catalyst caused this electron-poor aromatic C-H to be activated effectively and unactivated alkenes are also suitable for this reaction.