Synthesis of Diamondoid CarboxylicAcids
Synthesis of Diamondoid CarboxylicAcids
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金刚烷羧酸的合成
DOI：
10.1055/s-0031-1289617
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发表时间：
2012
期刊：
影响因子：
--
通讯作者：
Peter R. Schreiner
中科院分区：
文献类型：
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作者：
Natalie A. Fokina;Boryslav A. Tkachenko;Jerremy E. P. Dahl;Robert M. K. Carlson;Andrey A. Fokin;Peter R. Schreiner
从相应的醇和溴化物出发，详细阐述了三金刚烷、[121]四金刚烷和[1（2，3）4]五金刚烷的顶端单羧酸、二羧酸和三羧酸、二金刚烷和三金刚烷的顶端二乙酸以及二金刚烷和三金刚烷的中间丙酸的合成方法。所得到的金刚烷酸的特征在于其甲酯衍生物。
Procedures for the synthesis of apical mono-, di-, and tricarboxylic acids of triamantane,[121] tetramantane, and [1 (2, 3) 4] pentamantane, apical diacetic acids of diamantane and triamantane, as well as medial propionic acids of diamantane and triamantane were elaborated starting from the corresponding alcohols and bromides. The obtained diamondoid acids were characterized as their methyl ester derivatives.