Gold-catalyzed intermolecular hydroamination of allenes: First example of the use of an aliphatic amine in hydroamination
Gold-catalyzed intermolecular hydroamination of allenes: First example of the use of an aliphatic amine in hydroamination
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DOI：
10.1055/s-2007-984501
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发表时间：
2007-07-03
期刊：
影响因子：
2
通讯作者：
Yamamoto, Yoshinori
中科院分区：
文献类型：
--
作者：
Nishina, Naoko;Yamamoto, Yoshinori
在甲苯中，在阳离子金（I）催化剂的存在下，在80 ℃下用吗啉处理联烯，以良好至中等的产率得到相应的烯丙基化合物。据我们所知。这是用脂族胺进行金催化的分子间氢化胺化的第一个实施例。
Treatment of allenes with morpholine in the presence of cationic gold(I) catalyst ill toluene at 80 degrees C gave the corresponding allylic airlines in good to moderate yields. To the best of our knowledge. this is the first example for carrying out the gold-catalyzed intermolecular hydroamination with an aliphatic amine.