Aggregation of Synthetic Zinc Complexes of Cyclotetrapyrroles
Aggregation of Synthetic Zinc Complexes of Cyclotetrapyrroles
复制标题
环四吡咯合成锌配合物的聚集
DOI：
10.1246/cl.1996.639
复制
发表时间：
1996
影响因子：
1.6
通讯作者：
R. Tanikaga
中科院分区：
文献类型：
--
作者：
H. Tamiaki;Takayuki Kubota;R. Tanikaga
合成了具有31-羟基和131-酮羰基的环四吡咯锌配合物。电子光谱和圆二色吸收光谱表明，这些化合物在极性较低的有机溶剂中自聚集形成低聚物，是光合触角中细菌叶绿素d自然聚集体的良好模型。
Zinc complexes of cyclotetrapyrroles possessing 31-hydroxyl and 131-keto carbonyl groups were prepared. The electronic and circular dichroism absorption spectra showed that these compounds self-aggregated in less polar organic solvents to form oligomers, which are good models for natural aggregates of bacteriochlorophyll-d in photosynthetic antennae.