Layer-by-layer assembly of charged poly(phenylacetylene)s with induced macromolecular helicity.
Layer-by-layer assembly of charged poly(phenylacetylene)s with induced macromolecular helicity.
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DOI：
10.1039/b507863f
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发表时间：
2005-08
影响因子：
4.9
通讯作者：
Katsuhiro Maeda;Yasuaki Matsushita;M. Ezaka;E. Yashima
中科院分区：
文献类型：
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作者：
Katsuhiro Maeda;Yasuaki Matsushita;M. Ezaka;E. Yashima
在水溶液中，小分子手性客体诱导的带电聚苯乙炔的大分子螺旋度可以通过交替沉积带相反电荷的非手性聚电解质来保持，从而得到具有大分子螺旋度记忆的光学活性多层膜。
The macromolecular helicity of charged poly(phenylacetylene)s induced by small chiral guests in water can be retained by the alternative deposition of achiral polyelectrolytes with opposite charges, resulting in optically active multilayer thin films with a macromolecular helicity memory.