Molecular stereochemistry of [FeIII(TPP)(OCOCF3)].
Molecular stereochemistry of [FeIII(TPP)(OCOCF3)].
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[FeIII(TPP)(OCOCF3)] 的分子立体化学。
DOI：
10.1107/s010827019401334x
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发表时间：
1995
期刊：
影响因子：
--
通讯作者：
Wilson,LJ
中科院分区：
文献类型：
--
作者：
Moy,SA;González,JA;Wilson,LJ
meso-Tetraphenylporphinato）（trifluoroacetate）Fe（III），[Fe（C2 F302）（C~ H28 N4）]，是由中心Fe原子与四个吡咯N原子赤道配位，轴向与三氟乙酸根O原子配位而成.平均Fe-N键距为2.054（5），Fe原子从卟吩合平面位移0.483（1）。Fe-O键距为1.921（4）A。离面位移和Fe-N键长表明Fe原子处于高自旋态。
Abstract (meso-Tetraphenylporphinato)(trifluoroacetato) iron (III),[Fe (C2F302)(C~ H28N4)], consists of a central Fe atom equatorially coordinated to four pyrrole N atoms and axially coordinated to an O atom of the trifluoroacetate group. The average Fe--N bond distance is 2.054 (5), & and the Fe atom is displaced 0.483 (1) A from the porphinato plane. The Fe--O distance is 1.921 (4) A. The out-of-plane displacement and the Fe--N bond lengths indicate that the Fe atom is in a high-spin state.