ELUCIDATION OF ABSOLUTE CONFIGURATION OF OPHIORRHISIDE A BY COMPARISON OF ECD SPECTRA WITH THAT OF MODEL CHIRAL COMPOUND HAVING A 1,2,3,4-TETRAHYDRO-β-CARBOLIN-3-ONE SKELETON
ELUCIDATION OF ABSOLUTE CONFIGURATION OF OPHIORRHISIDE A BY COMPARISON OF ECD SPECTRA WITH THAT OF MODEL CHIRAL COMPOUND HAVING A 1,2,3,4-TETRAHYDRO-β-CARBOLIN-3-ONE SKELETON
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DOI：
10.3987/com-20-14351
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发表时间：
2021-01-01
期刊：
影响因子：
0.6
通讯作者：
Kitajima, Mariko
中科院分区：
文献类型：
--
作者：
Onozawa, Tadayoshi;Kogure, Noriyuki;Kitajima, Mariko
从 L-亮氨酸合成了在 C-1 处具有取代基的手性 1,2,3,4-四氢-β-咔啉-3-酮，并用于阐明 Ophiorrhiside A（一种单萜葡萄糖吲哚生物碱）在 C-3 处的绝对构型。
A chiral 1,2,3,4-tetrahydro-beta-carbolin-3-one having a substituent at C-1 was synthesized from L-leucine and used to elucidate the absolute configuration at C-3 of ophiorrhiside A, a monoterpenoid glucoindole alkaloid.