One-Step Preparation of Functionalized (E)-Vinylsilanes from Aldehydes
One-Step Preparation of Functionalized (E)-Vinylsilanes from Aldehydes
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DOI：
10.1021/ol201833u
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发表时间：
2011-09-16
期刊：
影响因子：
5.2
通讯作者：
Anderson, Edward A.
中科院分区：
文献类型：
--
作者：
Lim, Diane S. W.;Anderson, Edward A.
官能化的（E）-乙烯基硅烷已经从广泛的醛通过铬（II）介导的与新型二卤甲基硅烷试剂的烯化在一个步骤中以中等至优异的产率和优异的立体选择性制备。
Functionalized (E)-vinylsilanes have been prepared in one step from a wide range of aldehydes, via a chromium(II)-mediated olefination with novel dihalomethylsilane reagents, in moderate to excellent yields and with excellent stereoselectivity.