Quantum control of molecular handedness in a randomly oriented racemic mixture using three polarization components of electric fields
Quantum control of molecular handedness in a randomly oriented racemic mixture using three polarization components of electric fields
复制标题
使用电场的三个极化分量对随机取向的外消旋混合物中分子旋向性的量子控制
DOI：
10.1063/1.1472512
复制
发表时间：
2002
影响因子：
4.4
通讯作者：
Y. Fujimura
中科院分区：
文献类型：
--
作者：
K. Hoki;L. González;Y. Fujimura
提出了一种新的激光控制方案，用于从随机取向的外消旋混合物中获得大量的对映体浓缩。这是通过使用电场的三个极化分量来实现的；一个用于定向，另外两个用于控制手性。通过对轴手性H_2POSH分子对映体浓缩的数值模拟，验证了该方法的有效性。
A new laser control scenario is presented for obtaining substantial amounts of enantiomeric enrichment from a randomly oriented racemic mixture. This is carried out by using three polarization components of electric fields; one is used for orientation, the other two for controlling the chirality. The effectiveness is demonstrated by numerical simulations on the enantiomeric enrichment of the axial chiral H 2 POSH molecule.