A terminal borylene ruthenium complex: From B-H activation to reversible hydrogen release
A terminal borylene ruthenium complex: From B-H activation to reversible hydrogen release
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DOI：
10.1021/ja805164n
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发表时间：
2008-10-01
影响因子：
15
通讯作者：
Sabo-Etienne, Sylviane
中科院分区：
文献类型：
--
作者：
Alcaraz, Gilles;Helmstedt, Ulrike;Sabo-Etienne, Sylviane
从RuHCl（H-2）（PCy 3）（2）出发，通过均三甲苯硼烷的B-H双键活化和伴随的氢释放，得到了末端钌均三甲苯硼烷配合物，该过程是显著可逆的。
Starting from RuHCl(H-2)(PCy3)(2), a terminal ruthenium mesitylborylene complex was obtained via double B-H bond activation of mesitylborane and concomitant release of dihydrogen, such a process being remarkably reversible.