Hydride encapsulation in s-block metal inverse crown chemistry

Hydride encapsulation in s-block metal inverse crown chemistry
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DOI:
10.1039/b110117j
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发表时间:
2002-01-01
影响因子:
4.9
通讯作者:
Rowlings, RB
Rowlings, RB
中科院分区:
化学2区
文献类型:
--
作者:
Gallagher, DJ;Henderson, KW;Rowlings, RB

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通过合成二钠二镁二异丙胺[Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)],,建立了一种新的“反冠”络合物,这是第一个表现出氢化物包裹、非平面八角形“主体”环或溶剂稳定的此类络合物。
A new category of 'inverse crown' complex has been established through the synthesis of the disodium-dimagnesium diisopropylamide [Na2Mg2{N(Pr-i)(2)}(4)(mu-H)(2).(toluene)(2)], the first such complex to exhibit hydride encapsulation, a non-planar octagonal 'host' ring or solvent stabilisation.