Microwave-specific acceleration of a retro-Diels–Alder reaction
Microwave-specific acceleration of a retro-Diels–Alder reaction
复制标题
逆狄尔斯阿尔德反应的微波特异性加速
DOI：
10.1039/d0cc04584e
复制
发表时间：
2020
影响因子：
4.9
通讯作者：
Dudley, Gregory B.
中科院分区：
文献类型：
--
作者：
Frasso, Michael A.;Stiegman, Albert E.;Dudley, Gregory B.
根据Arrhenius动力学和测量的反应混合物温度，通过微波(MW)加热到高于预期的速率来加速高温逆向Diels-Alder反应。观察结果与极性反应物相对于反应混合物中其他较低极性组分的选择性微波加热是一致的。
A high-temperature retro-Diels–Alder reaction is accelerated by microwave (MW) heating to rates higher than expected based on Arrhenius kinetics and the measured temperature of the reaction mixture. Observations are consistent with selective MW heating of the polar reactant relative to other, less polar components of the reaction mixture.