Synthesis of an azadioxa-planar triphenylborane and investigation of its structural and photophysical properties
Synthesis of an azadioxa-planar triphenylborane and investigation of its structural and photophysical properties
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氮杂二氧平面三苯基硼烷的合成及其结构和光物理性质的研究
DOI：
10.1039/d0cc08331c
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发表时间：
2021
影响因子：
4.9
通讯作者：
Oi S.
中科院分区：
文献类型：
--
作者：
Kitamoto Y.;Oda K.;Ogino K.;Hiyama K.;Kita H.;Hattori T.;Oi S.
本文报道了首次通过芳香族亲核取代反应成功地合成了平面三苯硼烷1。杂原子桥接的1具有优异的平面性。它的结构和物理性质是可调的，通过改变桥原子。
We report here the first successful synthesis of planar triphenylborane 1 with the phenyl groups bridged by oxygen and nitrogen atoms via double nucleophilic aromatic substitution reaction. The hetero atom-bridged 1 has excellent planarity. Its structural and photophysical properties are tunable by altering the bridging atoms.