Metal-metal d-d interaction through the discrete stacking of mononuclear M(II) complexes (M = Pt, Pd, and Cu) within an organic-pillared coordination cage.
Metal-metal d-d interaction through the discrete stacking of mononuclear M(II) complexes (M = Pt, Pd, and Cu) within an organic-pillared coordination cage.
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DOI：
10.1021/ja053009f
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发表时间：
2005-07
影响因子：
15
通讯作者：
M. Yoshizawa;K. Ono;K. Kumazawa;Tatsuhisa Kato;M. Fujita
中科院分区：
文献类型：
--
作者：
M. Yoshizawa;K. Ono;K. Kumazawa;Tatsuhisa Kato;M. Fujita
两个分子的平面MII（acac）2配合物（M = Pt，Pd和Cu; acac =乙酰丙酮）有效地堆叠在有机柱撑的配位笼内，表现出特征光谱（对于M = Pt和Pd）和电子自旋-自旋耦合（对于M = Cu）归因于金属-金属相互作用。
Two molecules of planar MII(acac)2 complexes (M = Pt, Pd, and, Cu; acac = acetylacetonato) are efficiently stacked within an organic-pillared coordination cage, exhibiting characteristic spectroscopies (for M = Pt and Pd) and electron spin-spin coupling (for M = Cu) attributable to metal-metal interaction.