Effects of complexation with 18-crown-6 on the hypernucleofugality of phenyl-λ3-iodanyl groups.: Synthesis of vinyl-λ3-iodane•18-Crown-6 complex
Effects of complexation with 18-crown-6 on the hypernucleofugality of phenyl-λ3-iodanyl groups.: Synthesis of vinyl-λ3-iodane•18-Crown-6 complex
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DOI：
10.1021/ol050858z
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发表时间：
2005-07-07
期刊：
影响因子：
5.2
通讯作者：
Shiro, M
中科院分区：
文献类型：
--
作者：
Ochiai, M;Suefuji, T;Shiro, M
4-tert-Butyl-1-cyclohexenyl(phenyl)(tetrafluoroborato)-lambda(3)-iodane forms a discrete supramolecular complex by the reaction with 18-crown-6. Solvolysis of the cyclohexenyl-lambda(3)-iodane in the presence of 18-crown-6 indicates that the complexation with 18-crown-6 tends to decrease the leaving group ability of hypervalent phenyl-lambda(3)-iodanyl groups.
