Structural revision and total synthesis of caraphenol B and C.
Structural revision and total synthesis of caraphenol B and C.
复制标题
卡拉酚B和C的结构修正和全合成。
DOI：
10.1021/ol2022406
复制
发表时间：
2011
期刊：
影响因子：
5.2
通讯作者：
Brill,ZacharyG
中科院分区：
文献类型：
--
作者：
Snyder,ScottA;Brill,ZacharyG
Chemical syntheses of two stereochemically unique resveratrol dimers, caraphenols B and C, have shown that their structures are misassigned. Thoughts on their potential chemical etiology led to an alternate structural proposal that has been confirmed through synthesis, one indicating that the substituents on their respective indane systems exist in a relativetrans,transorientation rather than the originally postulated all-cisarrangement.
