Michael radical additions -: Two short efficient syntheses of (+)-conocephalenol from (R)-pulegone
Michael radical additions -: Two short efficient syntheses of (+)-conocephalenol from (R)-pulegone
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DOI：
10.1016/s0040-4020(99)00636-5
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发表时间：
1999-09-10
期刊：
影响因子：
2.1
通讯作者：
Hakiki, A
中科院分区：
文献类型：
--
作者：
Cossy, J;Bouzbouz, S;Hakiki, A
本文报道了由（R）-胡薄荷酮合成（+）-锥头酚的两种简便有效的方法。其关键步骤是在酸性条件下叔基与烯酮的自由基加成和分子内羟醛环化反应。(C)1999 Elsevier Science Ltd.保留所有权利。
Two short and efficient syntheses of (+)-conocephalenol are described from (R)-pulegone. The key steps are radical additions of tertiary radicals to enones and an intramolecular aldol cyclization under acidic conditions. (C) 1999 Elsevier Science Ltd. All rights reserved.