Room-temperature highly efficient Suzuki–Miyaura reactions in water in the presence of Stilbazo
Room-temperature highly efficient Suzuki–Miyaura reactions in water in the presence of Stilbazo
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DOI：
10.1039/c000739k
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发表时间：
2010-06
期刊：
影响因子：
9.8
通讯作者：
Yiyuan Peng;Jinbiao Liu;X. Lei;Z. Yin
中科院分区：
文献类型：
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作者：
Yiyuan Peng;Jinbiao Liu;X. Lei;Z. Yin
以二苯乙烯（二苯乙烯-4,4′-双[（1-偶氮）-3,4-二羟基苯]-2,2′-二磺酸二铵盐）为催化剂，建立了室温下无配体Suzuki-Miyaura反应的高效催化体系。在温和的条件下，碳碳键的形成效率高，官能团耐受性好。
An efficient catalytic system for the ligand-free Suzuki–Miyaura reaction in water at room temperature is disclosed, promoted by Stilbazo (stilbene-4,4′-bis[(1-azo)-3,4-dihydroxybenzene]-2,2′-disulfonic acid diammonium salt). The desired carbon–carbon bond formation proceeded well under mild conditions with high efficiency and good functional group tolerance.