Determination of the Nature of the Structural Phase Transitions in 122 Pnictide Systems

Determination of the Nature of the Structural Phase Transitions in 122 Pnictide Systems
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122 磷元素体系中结构相变性质的测定

DOI:
10.1088/1742-6596/391/1/012134
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发表时间:
2012
期刊:
Conference Series
影响因子:
--
通讯作者:
Loudon J
Loudon J
中科院分区:
--
文献类型:
--
作者:
Loudon J

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用透射电子显微镜研究了新近发现的铁基超导体SrFe2As2和Ba(Fe0.985Co0.015)2As2的四方相到正交相的相变。我们使用的方法,测量的空间分辨序参量,并表明,而在SrFe2As 2的过渡是一个一阶马氏体相变,Ba(Fe0.985Co0.015)2As 2显示连续变化的序参量的相变发生。这通常表明二阶相变,但情况似乎更复杂,因为在过渡期间,样品的不同区域具有不同的序参量值:这应该只发生在一阶变化中。
Transmission electron microscopy was used to investigate the tetragonal-to-orthorhombic phase transitions in SrFe 2 As 2 and Ba (Fe 0.985 Co 0.015) 2 As 2 which are members of the recently discovered iron-based superconductors. We use a method which measures the spatially-resolved order parameter and show that whereas the transition in SrFe 2 As 2 is a first-order martensitic phase change, Ba (Fe 0.985 Co 0.015) 2 As 2 shows a continuous change of the order parameter as the phase transition takes place. This would normally indicate a second order phase transition but the situation seems to be more complicated as, during the transition, different regions of the sample had different values of the order parameter: something which should only happen in a first order change.