Corrigendum: A Highly Active Bidentate Magnesium Catalyst for Amine-Borane Dehydrocoupling: Kinetic and Mechanistic Studies.

Corrigendum: A Highly Active Bidentate Magnesium Catalyst for Amine-Borane Dehydrocoupling: Kinetic and Mechanistic Studies.
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勘误表:用于胺-硼烷脱氢偶联的高活性双齿镁催化剂:动力学和机理研究。

DOI:
10.1002/chem.202000050
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发表时间:
2020
期刊:
Chemistry (Weinheim an der Bergstrasse, Germany)
影响因子:
--
通讯作者:
Ried ACA
Ried ACA
中科院分区:
--
文献类型:
--
作者:
Ried ACA

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在已发表的论文中,我们描述了根据韦伯斯特等人发表的方法合成Me2NH·BD 3的尝试,[1]在我们的手中,它提供了Me2NH·BH 3和Me2NH·BD 3的混合物。我们想澄清的是,在韦伯斯特等人的论文中,一个纯的Me2NH·BD 3样品是根据他们提供的数据合成的,任何关于他们的光谱可能被错误分配的暗示都是不正确的。作者对造成的不便表示歉意。在等式(1)中,存在错误,并且其应当为:
In the published paper, we described the attempted synthesis of Me2NH· BD3, according to the method published by Webster et al.,[1] which in our hands afforded a mixture of Me2NH· BH3 and Me2NH· BD3. We would like to clarify that in the paper Webster et al. a pure sample of Me2NH· BD3 was synthesised based on the data they presented, and any implication that their spectra may have been mis-assigned was incorrect. The authors apologise for any inconvenience. In the Equation (1) there is an error and it should read: