From Equilibrium Thermodynamics to Phase Equilibria
From Equilibrium Thermodynamics to Phase Equilibria
复制标题
从平衡热力学到相平衡
DOI：
10.1007/978-1-4757-6173-3_4
复制
发表时间：
1998
期刊：
影响因子：
--
通讯作者：
A. Mchale
中科院分区：
文献类型：
--
作者：
A. Mchale
传统的热力学是在理解和广泛接受物质的原子性质和晶体状态之前发展起来的。平衡态热力学的基本方程同样适用于描述机械或化学系统中能量传递和平衡的宏观或微观现象。然而，有意义的应用热力学量和关系，在理解相平衡不能完成没有充分认识的性质相考虑。
Traditional thermodynamics was developed prior to the understanding and broad acceptance of the atomistic nature of matter and the crystalline state. The fundamental equations of equilibrium thermodynamics are equally suitable in the description of macroscopic or microscopic phenomena of energy transfer and balance in mechanical or chemical systems. However, meaningful application of thermodynamic quantities and relationships in understanding phase equilibrium cannot be accomplished without full awareness of the nature of the phases under consideration.