Synthesis of a gable bis-porphyrin linked with a bicyclo[2.2.2]octadiene ring and its conversion into a conjugated planar bis-porphyrin
Synthesis of a gable bis-porphyrin linked with a bicyclo[2.2.2]octadiene ring and its conversion into a conjugated planar bis-porphyrin
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双环[2.2.2]辛二烯环连接的山墙双卟啉的合成及其转化为共轭平面双卟啉
DOI：
10.1039/b108391k
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发表时间：
2001
影响因子：
4.9
通讯作者：
N. Ono
中科院分区：
文献类型：
--
作者：
S. Ito;Ken;H. Uno;T. Murashima;N. Ono
通过在200 °C下加热，将可溶性的双环[2.2.2]辛烷连接的卟啉二聚体转化为不溶性的共轭卟啉二聚体，为共轭卟啉的过程控制提供了一种新的策略。
A soluble porphyrin dimer linked with bicyclo[2.2.2]octadiene was converted into insoluble conjugated porphyrin dimer by heating at 200 °C, this provides a new strategy for the process control of conjugated porphyrins.