Flavin-catalyzed generation of diimide: An environmentally friendly method for the aerobic hydrogenation of olefins
Flavin-catalyzed generation of diimide: An environmentally friendly method for the aerobic hydrogenation of olefins
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DOI：
10.1021/ja053976q
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发表时间：
2005-10-26
影响因子：
15
通讯作者：
Naota, T
中科院分区：
文献类型：
--
作者：
Imada, Y;Iida, H;Naota, T
第一个绿色和实用的方法“有氧加氢”涉及使用肼和有机催化剂进行了描述。在5-乙基-3-甲基异黄铵高氯酸盐（FlEt+·ClO 4-）催化剂存在下，烯烃与肼反应，在氧气气氛下加氢，得到相应的加氢产物，沿着的产物中只有对环境无害的水和分子氮。
The first green and practical method for “aerobic hydrogenation” involving the use of hydrazine and an organocatalyst is described. Olefins can be hydrogenated by treatment with hydrazine in the presence of a 5-ethyl-3-methyllumiflavinium perchlorate (FlEt+·ClO4-) catalyst under O2atmosphere to give the corresponding hydrogenated products in excellent yields along with environmentally benign water and molecular nitrogen as the only waste products.