Synthesis and solution properties of comblike poly(mono-n-alkyl itaconates). I. Poly(monodecyl itaconate)
Synthesis and solution properties of comblike poly(mono-n-alkyl itaconates). I. Poly(monodecyl itaconate)
复制标题
梳状聚衣康酸单正烷基酯的合成和溶液性质。
DOI：
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发表时间：
1989
期刊：
影响因子：
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通讯作者：
D. Radić
中科院分区：
文献类型：
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作者：
A. León;L. Gargallo;A. Horta;D. Radić
制备并聚合衣康酸与正癸醇单酯。将聚合物分级，并通过粘度计、尺寸排阻色谱（SEC）和光散射进行表征。一些常见的柔性和刚性聚合物的半经验关系，以获得无扰尺寸和构象参数。热力学和尺寸参数进行了测定和计算。与以前报道的类似化合物的结果进行了比较。
The monoester of itaconic acid with n-decyl alcohol was prepared and polymerized. The polymer was fractionated and characterized by viscometry, size-exclusion chromatography (SEC) and light scattering. Some of the common semiempirical relations for flexible and rigid polymers were used in order to obtain the unperturbed dimensions and the conformational parameters. Thermodynamic and dimensional parameters were determined and calculated. The results are compared with those reported previously for similar compounds.