Rational syntheses of novel linear chain rhodium(I)-semiquinonato complexes using redox reaction of Rh4(CO)12 cluster with o-benzoquinone derivatives
Rational syntheses of novel linear chain rhodium(I)-semiquinonato complexes using redox reaction of Rh4(CO)12 cluster with o-benzoquinone derivatives
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DOI：
10.1246/cl.2004.970
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发表时间：
2004-08-05
影响因子：
1.6
通讯作者：
Toriumi, K
中科院分区：
文献类型：
--
作者：
Mitsumi, M;Umebayashi, S;Toriumi, K
十二羰基四钠(0),Rh-4(CO)（12）与9,10-苯蒽醌衍生物的氧化还原反应得到了新的一维铑(I)-半醌配合物。通过x射线晶体结构分析，确定了两种具有直接Rh-Rh接触的典型线性链结构。
Redox reactions of dodecacarbonyltetrarhodium(0), Rh-4(CO)(12), with 9,10-phenanthraquinone derivatives gave novel one-dimensional rhodium(I)-semiquinonato complexes. Two typical linear chain structures with direct Rh-Rh contacts were determined by X-ray crystal structure analyses of the compounds.