Screening Synthesis Pathways for Biomass-Derived Sustainable Polymer Production
Screening Synthesis Pathways for Biomass-Derived Sustainable Polymer Production
复制标题
筛选生物质衍生的可持续聚合物生产的合成途径
DOI：
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发表时间：
2017
期刊：
影响因子：
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通讯作者：
N. Shah
中科院分区：
文献类型：
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作者：
Dongda Zhang;E. A. Rio;N. Shah
生物质衍生的可持续聚合物已被广泛研究，以取代石油基聚合物并满足不断增长的市场需求。由于生物质和聚合物种类的多样性，存在大量从生物质到聚合物的合成路线。然而，其生产和经济潜力从未得到评估。因此，在这项研究中，一个全面的反应网络，涵盖了20种聚合物的合成，包括新提出的生物聚合物和传统的聚合物，是第一次解决这一挑战。通过该网络，筛选了100多种合成途径，以确定最有前途的生物聚合物。三个原始的贡献结束。首先，从碳的角度来看，聚乙烯和1，4-环己二烯基聚合物被认为是最好的石油基聚合物和新提出的生物聚合物，可以从生物质中生产，分别，因为它们的最高的碳回收效率的生物质。
Sustainable polymers derived from biomass have been extensively investigated to replace petroleum-based polymers and fulfill the ever-increasing market demand. Because of the diversity of biomass and polymer categories, there exists a large number of synthesis routes from biomass to polymers. However, their productive and economic potentials have never been evaluated. Therefore, in this study, a comprehensive reaction network covering the synthesis of 20 polymers, including both newly proposed biopolymers and traditional polymers, is constructed to resolve this challenge for the first time. Through the network, over 100 synthesis pathways are screened to identify the most promising biopolymers. Three original contributions are concluded. First, from a carbon point of view, polyethylene and 1,4-cyclohexadiene-based polymers are found to be the best petroleum-based polymer and newly proposed biopolymers that can be produced from biomass, respectively, because of their highest carbon recovery efficiency of ∼...
什么是通量平衡分析？
影响因子：
46.9
作者：
通讯作者：
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影响因子：
3.7
作者：
A. Voll;W. Marquardt
通讯作者：
A. Voll;W. Marquardt
影响因子：
4.9
作者：
Ciriminna, Rosaria;Lomeli-Rodriguez, Monica;Pagliaro, Mario
通讯作者：
Pagliaro, Mario