Interfacial Adsorption of 1,10-Phenanthroline Complexes in Solvent Extraction Systems
Interfacial Adsorption of 1,10-Phenanthroline Complexes in Solvent Extraction Systems
复制标题
溶剂萃取系统中 1,10-菲咯啉配合物的界面吸附
DOI:
10.1246/bcsj.61.1159
复制
发表时间:
1988
影响因子:
4
通讯作者:
M. Fujishima
中科院分区:
文献类型:
--
作者:
H. Watarai;Y. Horii;M. Fujishima
A significant adsorptivity of tris(1,10-phenanthroline)iron(II), [Fe(phen)3]2+, at the interface of chloroform or carbon tetrachloride/0.1 M aqueous sodium chloride systems was determined by means of interfacial tension measurements at 25 °C. In the distribution systems of phen containing Zn(II) or Cu(II), a characteristic interfacial tension lowering was observed and interpreted in terms of an interfacial adsorption of metal–phen complexes.