Interfacial Adsorption of 1,10-Phenanthroline Complexes in Solvent Extraction Systems

Interfacial Adsorption of 1,10-Phenanthroline Complexes in Solvent Extraction Systems
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溶剂萃取系统中 1,10-菲咯啉配合物的界面吸附

DOI:
10.1246/bcsj.61.1159
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发表时间:
1988
影响因子:
4
通讯作者:
M. Fujishima
M. Fujishima
中科院分区:
化学3区
文献类型:
--
作者:
H. Watarai;Y. Horii;M. Fujishima

文献摘要

被引文献

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通过在 25 °C 下测量界面张力,确定了三(1,10-菲咯啉)铁 (II)、[Fe(phen)3]2+ 在氯仿或四氯化碳/0.1 M 氯化钠水溶液体系界面上的显着吸附性。在含有 Zn(II) 或 Cu(II) 的苯酚分布系统中,观察到特征界面张力降低,并根据金属-苯酚络合物的界面吸附进行解释。
A significant adsorptivity of tris(1,10-phenanthroline)iron(II), [Fe(phen)3]2+, at the interface of chloroform or carbon tetrachloride/0.1 M aqueous sodium chloride systems was determined by means of interfacial tension measurements at 25 °C. In the distribution systems of phen containing Zn(II) or Cu(II), a characteristic interfacial tension lowering was observed and interpreted in terms of an interfacial adsorption of metal–phen complexes.