Generation of fullerenyl cation (EtO)2P+(OH)CH2-C60+ from RC60-H and from RC60-C60R (R = CH2P(O)(OEt)2)
Generation of fullerenyl cation (EtO)2P+(OH)CH2-C60+ from RC60-H and from RC60-C60R (R = CH2P(O)(OEt)2)
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DOI：
10.1021/ja047483h
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发表时间：
2004-07-28
影响因子：
15
通讯作者：
Komatsu, K
中科院分区：
文献类型：
--
作者：
Murata, Y;Cheng, F;Komatsu, K
通过简单地将单官能化的氢富勒烯RC60−H或单键二聚体RC60− C60 R（R = CH2P（O）（OEt）2）溶解在氧化酸如H2SO4和FSO3H中，生成了一种新的富勒烯基阳离子（EtO）2P+（OH）CH2−C60+。阳离子也形成在CH2Cl2通过单电子氧化与铵自由基阳离子，并用于进一步官能化的C60。
A novel fullerenyl cation (EtO)2P+(OH)CH2−C60+was generated by simply dissolving the monofunctionalized hydrofullerene RC60−H or singly bonded dimer RC60−C60R (R = CH2P(O)(OEt)2) in oxidizing acids such as H2SO4and FSO3H. The cation was also formed in CH2Cl2by one-electron oxidation with aminium radical cation and was used for further functionalization of C60.