[Mn(C18H16N2O2)3](ClO4)2: A Polymeric 34- and 68-Membered Metallacyclic Network Forming a Novel Woven Polycatenated Structure†
[Mn(C18H16N2O2)3](ClO4)2: A Polymeric 34- and 68-Membered Metallacyclic Network Forming a Novel Woven Polycatenated Structure†
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DOI：
10.1002/anie.199505741
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发表时间：
1995-03
影响因子：
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通讯作者：
D. Goodgame;S. Menzer;A.M.L. Smith;D. Williams
中科院分区：
文献类型：
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作者：
D. Goodgame;S. Menzer;A.M.L. Smith;D. Williams
标题化合物的多链烷结构中存在两个34元和68元含锰大环与八面体环境中的锰原子的互穿网络（见图）。这种排列通过面对面和边缘面对面的π-π相互作用来稳定。这种复杂结构的形成机制尚不清楚。
Two interpenetrating networks of 34‐and 68‐membered manganese‐containing macrocycles with the manganese atoms in octahedral environments (see picture) are present in the polycatenane structure of the title compound. This arrangement is stabilized by face‐to‐face and edgo‐to‐face π–π interactions. The mechanism of formation of this complex structure is as yet unclear.