Emerging Applications of Nanoporous Molecular Crystals
Emerging Applications of Nanoporous Molecular Crystals
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DOI：
10.1021/acsanm.3c02188
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发表时间：
2023-08-29
影响因子：
5.9
通讯作者：
Miljanic，Ognjen S.
中科院分区：
文献类型：
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作者：
Robles，Alexandra;Miljanic，Ognjen S.
多孔分子晶体（PMC）是一类纳米多孔材料，由通过非共价相互作用结合在一起的离散的、典型的有机分子组成。虽然它们在许多特性上与结晶聚合物多孔材料（沸石、金属有机框架（MOF）和共价有机框架（COF））相似，但它们也具有明显的溶液和蒸汽加工能力，为融入设备提供了更好的可能性，并在多孔液体的创造中开辟了未探索的前沿。在本次聚焦中，我们将回顾和研究 PMC 在气体储存和分离、分析化学、多孔液体开发和其他领域的新兴应用示例。
Porous molecular crystals (PMCs) are a class of nanoporous materials composed of discrete, typically organic molecules held together by noncovalent interactions. While they parallel crystalline polymeric porous materials─zeolites, metal–organic frameworks (MOFs), and covalent organic frameworks (COFs)─in many of their characteristics, they are also distinctly solution- and vapor-processable, offering better possibilities for incorporation into devices and open unexplored frontiers in the creation of porous liquids. In this Spotlight, we will review and examine the examples of emerging applications of PMCs in gas storage and separations, analytical chemistry, the development of porous liquids, and other fields.