Reduction by metal–amine solutions: applications in synthesis and determination of structure
Reduction by metal–amine solutions: applications in synthesis and determination of structure
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金属胺溶液还原：在合成和结构测定中的应用
DOI：
10.1039/qr9581200017
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发表时间：
1958
期刊：
影响因子：
--
通讯作者：
H. Smith
中科院分区：
文献类型：
--
作者：
A. Birch;H. Smith
自从上一次对这一课题进行评述以来，主要是在合成和天然产物研究中开发金属胺溶液。理论上的发展主要是偶然的，对已经取得的成果几乎没有什么贡献。l我们在这里关注的是实际方面，但对理论背景的理解对于最好地使用试剂是必不可少的，因为技术上的变化是可能的。因此，下文在必要时提到了理论方面，但尽可能避免与以前的审查重叠。
WORK since the last reviews of the subject 1 y has been concerned chiefly with the exploitation of metal-nmine solutions in synthesis and in the investigation of natural products. Theoretical developments have been mainly incidental and have added little to what was already 1mown. l We are here concerned with the practical aspects but an appreciation of the theoretical background is essential for use of the reagents to the best purpose, since variations in technique are possible. So references to theoretical aspects are made below where necessary, but overlapping with earlier reviews has been avoided as far as possible.