Improved procedure for the oxidative cleavage of olefins by OsO4-NaIO4
Improved procedure for the oxidative cleavage of olefins by OsO4-NaIO4
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DOI：
10.1021/ol0400342
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发表时间：
2004-09-16
期刊：
影响因子：
5.2
通讯作者：
Jin, ZD
中科院分区：
文献类型：
--
作者：
Yu, WS;Mei, Y;Jin, ZD
OsO4-NaIO4 对烯烃的氧化裂解有时会因副产物的形成而导致收率低。研究发现，2,6-二甲基吡啶的加入可以抑制副反应，并显着提高这一经典反应的产率。
Oxidative cleavage of olefins by OsO4-NaIO4 Sometimes suffers from low yields due to the formation of side products. It is found that the addition of 2,6-lutidine can suppress the side reactions and dramatically improve the yield of this classic reaction.