Effect of Phase Separation on Helium Migration in Sodium Silicate Glasses

Effect of Phase Separation on Helium Migration in Sodium Silicate Glasses
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相分离对硅酸钠玻璃中氦迁移的影响

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发表时间:
1973
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影响因子:
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通讯作者:
J. Shelby
J. Shelby
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文献类型:
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作者:
J. Shelby

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Helium permeability, diffusion, and solubility were measured in sodium silicate glasses containing 0 to 40 mol% Na2O. These properties appear to depend on the substructure of the glass, since definite inflections occur in the curves of diffusivity and solubility vs composition at the boundaries of the two-phase region. Similar inflections occur for the activation energy for diffusion and enthalpy of solution at the phase boundaries. These effects are explained by use of a two-component diffusion model within the miscibility gap and a one-component model in the single-phase region.