Organic functionalization of epitaxial graphene on SiC through direct binding of transient radicals from the reaction mixture
Organic functionalization of epitaxial graphene on SiC through direct binding of transient radicals from the reaction mixture
复制标题
通过直接结合反应混合物中的瞬态自由基实现 SiC 上外延石墨烯的有机功能化
DOI：
10.1039/c6cc08632b
复制
发表时间：
2016
期刊：
影响因子：
--
通讯作者：
M. A. M. Jusoh
中科院分区：
文献类型：
--
作者：
Md. Zakir Hossain, H. Yoko;M. A. M. Jusoh
利用一种著名的反应混合物，开发了一种常用的、通用的石墨烯有机官能化的化学方法。在这里，我们报道了在制备格氏试剂过程中瞬时产生的取代芳基或烷基自由基与预装在反应容器中的石墨烯样品的化学结合。
A common and versatile chemical approach for organic functionalization of graphene using a well known reaction mixture has been developed. Here we report the chemical binding of substituted aryl or alkyl radicals, transiently generated during the preparation of Grignard reagents, onto a graphene sample preloaded in a reaction vessel.