Single step fluorination of dialkylphosphites: trichloroacetonitrile-KF as an efficient reagent for the synthesis of dialkyl fluorophosphates

Single step fluorination of dialkylphosphites: trichloroacetonitrile-KF as an efficient reagent for the synthesis of dialkyl fluorophosphates
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DOI:
10.1016/j.tetlet.2008.02.051
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发表时间:
2008-03-31
影响因子:
1.8
通讯作者:
Dubey, D. K.
Dubey, D. K.
中科院分区:
化学4区
文献类型:
--
作者:
Gupta, A. K.;Acharya, J.;Dubey, D. K.

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使用三氯乙腈和KF混合物是一种有效的试剂,通过在一个锅中原位形成二烷基氯磷酸盐,将二烷基亚磷酸酯直接转化为相应的二烷基氟磷酸盐。(C) 2008 Elsevier Ltd版权所有。
The use of trichloroacetonitrite and KF mixture is described as an efficient reagent for the direct conversion of dialkylphosphites to their corresponding dialkyl fluorophosphates via in situ formation of dialkyl chlorophosphates in one-pot. (C) 2008 Elsevier Ltd. All rights reserved.