The Reactions of the Radical with Molecules Relevant to Combustion and Atmospheric Chemistry
The Reactions of the Radical with Molecules Relevant to Combustion and Atmospheric Chemistry
复制标题
自由基与燃烧和大气化学相关分子的反应
DOI：
10.1142/9789814317184_0005
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发表时间：
1996
期刊：
影响因子：
56.9
通讯作者：
M. Lin
中科院分区：
文献类型：
--
作者：
D. Yang;M. Lin
近年来，由于氰自由基在许多反应过程中所起的重要作用，人们对氰自由基与各种化合物的反应产生了很大的兴趣。它已被证明是一个重要的燃烧物种，特别是在含氮燃料系统，包括硝胺高能材料。在诸如RDX（六氢-1，3，5-三硝基-1，3，5-三嗪）的硝胺的燃烧中，CN自由基已被证明参与与HCN、NO、N2 O、NO2、CO2和其他物质反应的初级和次级火焰区<$1。CN反应也被认为在土卫六的大气中起着重要作用。土卫六有一个巨大的大气层，其温度足以维持大量的氮气，甲烷，氨和不饱和烃的气相。Yung等人认为，不饱和碳氢化合物中的氯化萘是土卫六大气中含氯化萘有机分子增长的原因。的
In recent years, there has been much interest in the reactions of the cyanogen radical (CN) with various compounds due to the recognition of the important role it plays in many reactive processes. It has been shown to be an important combustion species, particularly in N-containing fuel systems including nitramine energetic materials. In the combustion of nitramines such as RDX (hexahydro-1, 3, 5-trinitro-1, 3, 5-triazine), CN radicals have been shown to be involved in the primary and secondary flame zones¹ in reactions with HCN, NO, N2O, NO2, CO2, and other species. CN reactions are also proposed to play an important role in the atmosphere of Titan. Titan has a massive atmosphere whose temperature is warm enough to maintain significant amounts of nitrogen, methane, ammonia, and unsaturated hydrocarbons in the gas phase. Yung et al. ² have suggested that CN addition to unsaturated hydrocarbons is responsible for the growth of CN-containing organic molecules in Titan's atmosphere. The