Cyclopolymerization of (2S,3S,4S,5S)-1,2:5,6-Diepithio-3,4-dimethoxy- hexane Leading to a Novel Polymer with a Cyclic Sulfide Unit Possessing High Ag+- and Cu2+-Binding Characteristics
Cyclopolymerization of (2S,3S,4S,5S)-1,2:5,6-Diepithio-3,4-dimethoxy- hexane Leading to a Novel Polymer with a Cyclic Sulfide Unit Possessing High Ag+- and Cu2+-Binding Characteristics
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(2S,3S,4S,5S)-1,2:5,6-二硫代-3,4-二甲氧基-己烷的环聚合生成具有环状硫醚单元的新型聚合物，该聚合物具有高Ag和Cu2结合特性
DOI：
10.1021/ma961635e
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发表时间：
1997
期刊：
影响因子：
5.5
通讯作者：
T. Kakuchi
中科院分区：
文献类型：
--
作者：
T. Satoh;D. Kitazawa;H. Hashimoto;K. Yokota;T. Kakuchi
通过二环硫醚(2S,3S,4S,5S)-1,2:5,6-二环硫基-3,4-二甲氧基己烷的阳离子和阴离子环聚合反应合成了主要由五元环单元(2R,3S,4S,5S)-3,4-二甲氧基-1硫代环戊烷单元组成的聚合物。
A polymer mainly composed of five-membered cyclic units, i.e. the (2R,3S,4S,5S)-3,4-dimethoxy-1thiacyclopentane unit, has been synthesized by the cationic and anionic cyclopolymerizations of the diepisulfide (2S,3S,4S,5S)-1,2:5,6 -diepithio-3,4-dimethoxyhexane