Reaction of Diazo Compounds with Organoboron Compounds
Reaction of Diazo Compounds with Organoboron Compounds
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DOI：
10.1002/chin.201405243
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发表时间：
2013-10
期刊：
影响因子：
--
通讯作者：
Huan Li;Yan Zhang;Jianbo Wang
中科院分区：
文献类型：
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作者：
Huan Li;Yan Zhang;Jianbo Wang
综述了重氮化合物与有机硼化合物的无过渡金属反应。这种类型的反应提供了形成C-C、C-B和C-Si键的替代方法。此外，通过使用甲苯磺酰腙作为重氮化合物前体和硼酸/酯作为硼底物，这种类型的反应在有机合成中变得实用。这篇简短的评论涵盖了这一领域的最新发展，并介绍了历史背景。1引言2重氮化合物与有机硼烷的反应3重氮化合物与硼酸和相关有机硼的反应4重氮化合物与硼酸酯的反应5结束语
The transition-metal-free reactions of diazo compounds with organoboron compounds are reviewed. This type of reaction provides an alternative approach for the formation of C–C, C–B, and C–Si bonds. Moreover, by using tosylhydrazones as diazo compound precursors and boronic acids/esters as the boron substrates, this type of reaction becomes of practical use in organic synthesis. This short review covers the recent developments of this area with an introduction to the historical background. 1 Introduction 2 Reaction of Diazo Compounds with Organoboranes 3 Reactions of Diazo Compounds with Boronic Acids and Related Organoborons 4 Reaction of Diazo Compounds with Boronic Esters 5 Concluding Remarks