DYNAMIC STEREOCHEMISTRY OF SYMMETRICALLY BUT DIFFERENTLY SUBSTITUTED DIPHOSPHANES
DYNAMIC STEREOCHEMISTRY OF SYMMETRICALLY BUT DIFFERENTLY SUBSTITUTED DIPHOSPHANES
复制标题
对称但不同取代的二磷烷的动态立体化学
DOI：
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发表时间：
1986
期刊：
影响因子：
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通讯作者：
J. Hünerbein
中科院分区：
文献类型：
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作者：
R. Appel;B. Brück;F. Knoch;J. Hünerbein
摘要 过去几年我们在波恩的工作主要兴趣在于具有多重键的磷碳化合物领域。除了新型化合物的合成之外，我们对 PC- 和 CC- 双键之间惊人的相似性特别感兴趣，这可以通过 E/Z 异构体的证据和周环反应的明确指示来证明。
Abstract The main interest of our work in Bonn during the last years was in the field of phosphorus-carbon compounds with multiple bonds. Beside the synthesis of new classes of compounds we were particularly interested in the amazing analogy between the PC- and the CC-double bond, which could be proved by evidence of E/Z isomers and a clear indication of pericyclic reactions.