Synthesis and structure of a binuclear Cu(II) complex of 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol
Synthesis and structure of a binuclear Cu(II) complex of 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol
复制标题
DOI：
10.3390/i7050179
复制
发表时间：
2006-05-01
影响因子：
5.6
通讯作者：
Butcher, Ray
中科院分区：
文献类型：
--
作者：
Marvey, Bassie B.;Gultneh, Yilma;Butcher, Ray
报道了双核三齿配体 1,3-双[N,N-双(2-吡啶甲基)氨基]丙-2-醇 (I) 的 Cu(II) 配合物的合成和晶体结构。 I 中的两个螯合双环吡啶胺臂通过 2-羟丙基与 Cu(II) 相连，在稍微扭曲的方形平面几何形状中配位，得到 [Cu-2(I)(OH2)(Cl)](ClO4)(3) 中心点 2H(2)O (II)。 II 的晶体数据：三斜晶系，空间群 P (1)，晶胞尺寸为 a = 13.345 (4) 埃，b = 13.873 (4) 埃，c = 12.867 (2) 埃，α = 111.68 (2) 度，β = 100.34 (2) 度，gamma = 65.83 ( 2) 度，V = 2018.4 ( 9) 埃(3)，F. W. = 962.46，rho(calc) = 1.583 g cm(-3)，Z = 2，mu = 13.93 cm(-1)。
The synthesis and crystal structure of Cu(II) complex of a binucleating tridentate ligand 1,3-bis [N, N-bis(2-picolyl) amino] propan-2-ol (I) is being reported. The two chelating bispicolylamine arms in I are tethered by a 2-hydroxypropyl group with Cu( II) coordinating in a slightly distorted square planar geometry to give [Cu-2( I)(OH2)(Cl)](ClO4)(3) center dot 2H(2)O (II). The crystal data for II: Triclinic, space group P (1) over bar with cell dimensions of a = 13.345 (4) angstrom, b = 13.873 ( 4) angstrom, c = 12.867 (2) angstrom, alpha = 111.68 (2)degrees, beta = 100.34 (2)degrees, gamma = 65.83 ( 2)degrees, V = 2018.4 ( 9) angstrom(3), F. W. = 962.46, rho(calc) = 1.583 g cm(-3) for Z = 2,mu = 13.93 cm(-1).