Catalytic Transfer Functionalization through Shuttle Catalysis
Catalytic Transfer Functionalization through Shuttle Catalysis
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DOI：
10.1021/acscatal.6b02333
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发表时间：
2016-11-01
期刊：
影响因子：
12.9
通讯作者：
Morandi, Bill
中科院分区：
文献类型：
--
作者：
Bhawal, Benjamin N.;Morandi, Bill
在这方面，我们描述了一种新兴的催化类型，使化学实体的催化可逆转移超出了公认的转移氢化反应。穿梭催化促进小分子（例如，CO、HCN）或等键过程中两种底物之间的反应性中间体。在许多情况下，这些通常更安全的工艺提供了前所未有的合成灵活性，并补充了其他催化成键和键断裂反应。
In this Perspective, we describe an emerging type of catalysis that enables the catalytic reversible transfer of chemical entities beyond the well-established transfer hydrogenation reactions. Shuttle catalysis facilitates the transfer of small molecules (e.g., CO, HCN) or reactive intermediates between two substrates in an isodesmic process. In many cases, these often safer processes provide unprecedented synthetic flexibility and complement other catalytic bond-forming and bond-breaking reactions.