Generation of circular dichroism from superposed porphyrin films
Generation of circular dichroism from superposed porphyrin films
复制标题
从叠加的卟啉薄膜产生圆二色性
DOI：
10.1002/chir.23302
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发表时间：
2021
期刊：
影响因子：
2
通讯作者：
Watarai Hitoshi
中科院分区：
文献类型：
--
作者：
Takechi Hideaki;Watarai Hitoshi
由非手性卟啉分子气相沉积而成，通过与平板表面平行摩擦而成单向取向的沉积玻璃，观察到了圆二色(CD)现象。圆二色谱依赖于板之间的扭转角和叠加板的数量。利用各平板的线性二向色性光谱和线性双折射光谱，用Mueller矩阵叠加计算得到的CD光谱与模拟的结果一致。
Circular dichroism (CD) was observed from the superposed porphyrin deposited glass plates, which were prepared by the vapor deposition of achiral porphyrin molecules and oriented to one direction by rubbing parallel to the surface of plate. The CD spectra depended on the twisted angle between the plates and the number of plates superposed. The observed CD spectra agreed with the simulated ones by the Mueller matrices superposition calculation using the observed linear dichroism spectra and linear birefringence spectra of each plate.