A New Atom-Economical and SelectiveSynthesis of Secondary and Tertiary Alkylamines by Means of Cp*IridiumComplex Catalyzed Multiple N-Alkylation of Ammonium Saltswith Alcohols without Solvent
A New Atom-Economical and SelectiveSynthesis of Secondary and Tertiary Alkylamines by Means of Cp*IridiumComplex Catalyzed Multiple N-Alkylation of Ammonium Saltswith Alcohols without Solvent
复制标题
Cp*铱配合物催化铵盐与醇的多重N-烷基化无溶剂新型原子经济选择性合成仲烷基胺和叔烷基胺
DOI：
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发表时间：
2009
期刊：
影响因子：
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通讯作者：
K. Fujita
中科院分区：
文献类型：
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作者：
R. Yamaguchi;Zhu Ming;Shoko Kawagoe;Chiho Asai;K. Fujita
在无溶剂条件下，用五甲基铱（Cp*Ir）配合物催化铵盐与伯、仲醇的多次N-烷基化反应，实现了一种新的原子经济、选择性合成仲、叔烷基胺的方法。
A new atom-economical and selective synthetic method for secondary and tertiary alkylamines has been achieved by means of (pentamethylcyclopentadienyl)iridium (Cp*Ir) complex catalyzed multiple N-alkylations of ammonium salts with primary and secondary alcohols without solvent.