A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii).
A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii).
复制标题
DOI：
10.1039/d0cc02382e
复制
发表时间：
2020-05
影响因子：
4.9
通讯作者：
Moya A. Hay;Arup Sarkar;G. Craig;Katie E. R. Marriott;Claire Wilson;G. Rajaraman;M. Murrie
中科院分区：
文献类型：
--
作者：
Moya A. Hay;Arup Sarkar;G. Craig;Katie E. R. Marriott;Claire Wilson;G. Rajaraman;M. Murrie
第一个三角双锥Fe（ii）配合物显示缓慢弛豫的磁化强度已被隔离，发现这种行为是通过一个大的磁各向异性（D = -27.5 cm-1）和伪D3 h对称性在Fe（ii）中心的组合，通过从头算和磁性研究调查。
The first trigonal bipyramidal Fe(ii) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = -27.5 cm-1) and a pseudo-D3h symmetry at the Fe(ii) centre, as investigated through ab initio and magnetic studies.