Bifunctional AgOAc-catalyzed asymmetric reactions.
Bifunctional AgOAc-catalyzed asymmetric reactions.
复制标题
DOI：
10.1039/c001089h
复制
发表时间：
2010-06
影响因子：
4.9
通讯作者：
Qing‐An Chen;Duo-Sheng Wang;Yong‐Gui Zhou
中科院分区：
文献类型：
--
作者：
Qing‐An Chen;Duo-Sheng Wang;Yong‐Gui Zhou
介绍了用于不对称反应的新型双功能agoa催化剂的发现和进展。在这个双功能过程中，AgOAc作为一种高效的Lewis酸催化剂，同时通过醋酸促进活性氢的去质子化作为碱。双官能团的策略为C-C和C-N键的立体选择性构建提供了一个很好的机会。
The discovery and progress of new bifunctional AgOAc-based catalysts for asymmetric reactions is described. In this bifunctional procedure, AgOAc acts as an efficient Lewis acid catalyst as well as a base through the deprotonation of active hydrogen promoted by acetate. The bifunctional strategy offers a great opportunity to establish new fundamentals for stereoselective construction of C-C as well as C-N bonds.