Reversible flexible structural changes in multidimensional MOFs by guest molecules (I2, NH3) and thermal stimulation
Reversible flexible structural changes in multidimensional MOFs by guest molecules (I2, NH3) and thermal stimulation
复制标题
客体分子（I2、NH3）和热刺激引起的多维 MOF 的可逆柔性结构变化
DOI：
10.1016/j.jssc.2015.02.014
复制
发表时间：
2015-03-01
影响因子：
3.3
通讯作者：
Li, Jinping
中科院分区：
文献类型：
--
作者：
Chen, Yang;Li, Libo;Li, Jinping
合成了3种金属有机骨架（MOFs），分别为[Cu（INA）（2）]、[Cu（INA）（2）I-2]和[Cu（INA）（2）（H2O）（2）（NH3）（2）]，它们分别具有3D、2D和OD结构。报道了这些MOFs的可逆柔性结构变化。通过12的高温（60-100 ℃）刺激或NH3的环境温度刺激，[Cu（INA）（2）]（3D）转化为[Cu（INA）212]（2D）和[Cu（INA）（2）（H2O）（2）（NH3）（2）]（OD）;随着温度升高到150 ℃，MOF变回其原始形式。通过这种方式，这种3D MOF在从污染的水和空气中捕获I-2和NH3方面具有潜在的应用。采用XRD、TGA、SEM、NH3-TPD和气体吸附测试等手段对合成过程中的结构、形貌和性能变化进行了表征。(C)2015 Elsevier Inc. All rights reserved.
Three metal-organic frameworks (MOFs), [Cu(INA)(2)], [Cu(INA)(2)I-2] and [Cu(INA)(2)(H2O)(2)(NH3)(2)], were synthesized with 3D, 2D, and OD structures, respectively. Reversible flexible structural changes of these MOFs were reported. Through high temperature (60-100 degrees C) stimulation of 12 or ambient temperature stimulation of NH3, [Cu(INA)(2)] (3D) converted to [Cu(INA)212] (2D) and [Cu(INA)(2)(H2O)(2)(NH3)(2)] (OD); as the temperature increased to 150 degrees C, the MOFs changed back to their original form. In this way, this 3D MOF has potential application in the capture of I-2 and NH3 from polluted water and air. XRD, TGA, SEM, NH3-TPD, and the measurement of gas adsorption were used to describe the changes in processes regarding the structure, morphology, and properties. (C) 2015 Elsevier Inc. All rights reserved.