Synthesis and Characterization of (μ-Alkoxo)bis(μ-carboxylato)diruthenium Complexes, Na[Ru2(dhpta)(μ-O2CR)2] (dhptaH5 = 1,3-diamino-2-hydroxypropane tetraacetic acid). A Ruthenium Analogue of Model Systems for Iron-oxo Proteins
Synthesis and Characterization of (μ-Alkoxo)bis(μ-carboxylato)diruthenium Complexes, Na[Ru2(dhpta)(μ-O2CR)2] (dhptaH5 = 1,3-diamino-2-hydroxypropane tetraacetic acid). A Ruthenium Analogue of Model Systems for Iron-oxo Proteins
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(μ-烷氧基)双(μ-羧基)二钌络合物 Na[Ru2(dhpta)(μ-O2CR)2]（dhptaH5 = 1,3-二氨基-2-羟基丙烷四乙酸）的合成和表征。铁氧蛋白模型系统的建立
DOI：
10.1246/cl.1994.1853
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发表时间：
1994
影响因子：
1.6
通讯作者：
S. Yano
中科院分区：
文献类型：
--
作者：
T. Tanase;Masako Kato;Yasuko Yamada;Keiko Tanaka;Keomil Lee;Y. Sugihara;A. Ichimura;I. Kinoshita;Masa;Y. Sasaki;Yasuhiro Yamamoto;T. Nagano;S. Yano
The first ruthenium analogue of hemerythrin models with μ-alkoxo bridging, Na[Ru(dhpta)(μ-O2CR)2] (1: R = CH3, 2: R = C6H5, 3: R = C6H4-p-OH, 4: R = C6H4-p-NH2) have been prepared and characterized, and the crystal structure of 1 has been determined; these compounds undergo two one-electron reductions to the RuIIRuIII and RuIIRuII states with large separations (∼0.6 V) between the successive redox potentials, allowing the formation of stable mixed-valence species.
甲烷单加氧酶羟化酶成分中存在 mu-氧桥双核铁簇的证据。
DOI：
--
发表时间：
1988
期刊：
The Journal of biological chemistry
影响因子：
--
作者：
Fox,BG;Surerus,KK;Münck,E;Lipscomb,JD
通讯作者：
Lipscomb,JD