Bicontinuous microemulsions with extremely high temperature stability based on skin friendly oil and sugar surfactant

Bicontinuous microemulsions with extremely high temperature stability based on skin friendly oil and sugar surfactant
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基于亲肤油和糖表面活性剂的双连续微乳液,具有极高的温度稳定性

DOI:
10.1016/j.colsurfa.2012.10.039
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发表时间:
2013
期刊:
Colloids and Surfaces A: Physicochemical and Engineering Aspects
影响因子:
--
通讯作者:
Hellweg
Hellweg
中科院分区:
--
文献类型:
--
作者:
Schulreich;Angermann;Neubauer;Stehle;Richardt;Diekmann;Hellweg

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本文研究了基于异壬酸异壬酯 (Lanol​​ 99)、糖表面活性剂 Simulsol SL55 (C12/14G1.3)、D2O/水和助表面活性剂苯甲醇的微乳液的相行为,并确定了双连续相。使用小角中子散射 (SANS) 来表征双连续相的内部结构。实验中的温度范围为 261K 至 343K。发现所制备的微乳液的结构和相行为几乎不表现出温度依赖性。在低温下,微乳液内部的水以过冷液态存在。
In the present article the phase behavior of microemulsions based on isononyl isononanoate (Lanol 99), sugar surfactant Simulsol SL55 (C12/14G1.3), D2O/water, and the cosurfactant benzyl alcohol is studied and the bicontinuous phase is identified. Using small angle neutron scattering (SANS) the internal structure of the bicontinuous phase is characterized. In the experiments a temperature range from 261K to 343K was covered. The prepared microemulsions were found to exhibit nearly no temperature dependence with respect to their structure and phase behavior. At low temperatures inside the microemulsions water exists in a supercooled liquid state.
水-油-表面活性剂体系中的相行为和界面曲率
DOI: 10.1016/s1359-0294(96)80140-3
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